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Electrical double layer at the interface between mercury and dilute aqueous electrolyte solutions

✍ Scribed by K. Takahashi; R. Tamamushi


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
725 KB
Volume
16
Category
Article
ISSN
0013-4686

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✦ Synopsis


Differential-capacitance/potential curves were measured at the interface between mercury and dilute aqueous solutions of HClO,, NaClO,, NaOH, CH,COOH and NH,OH. In the potential region near the zero-charge potential, the double-layer behaviour of these systems is in agreement with Grahame's theory. In the negatively polarized region, the double-layer capacitances of the strong electrolyte systems decrease with decreasing concentration; this result suggests that the complete formation of the compact double-layer becomes difficult in very dilute solutions. The double-layer properties of CHICOOH and NH,OH solutions were compared with those of the strong electrolyte solutions. The difference between the weak and strong electrolyte systems in the differential capacitances in the negatively polarized region is explained in terms of the dissociation field effect on weak electrolytes. R&urn&La courbe de capacitance-differentielle-potentiel a 6th m&sur& & la interface entre mercure et des solutions aqueuse dilu&s des HClO*, NaCIO,, NaOH, CH&OOH et NH*OH. Dans la rdgion de potentiel de la charge z&o, le comportement de la couche double des systemes dtait d'accord avec la theorie de Grahame. Dans le domain polarisd n@ativement, la capacitance en cas des systbmes des Electrolytes fortes a diminu& avec la concentration diminuante. Ce resultat sugg&ret que la formation complete de la couche double peut &re difficile dans les solutions trts dilu&s. Les pro-pri&es de la couche double des solutions de CHsCOOH et de NH,OH 6taient cornpar& avec celles des solutions des Clectrolytes fortes. A ce qui conceme la capacitance differentielle dans le domain polaris nkgativement, la difference entre systkmes des &ctrolytes faibles et fortes a 6t6 expliqub en terme d'6ffet du champ de dissociation sur les dlectrolytes faibles. Zusammenfassung-Es wurden die differenzielle Kapazit%t-Potentialkurven an der Grenzschicht zwischen den Quecksilber und den verdiinten, wiissrigen Lijsungen von HCIOa, NaClO,, NaOH, CH,COOH und NHIOH gemessen. Beim Potentialbereich n&he z.p.c., stimmte das Doppelschichtsverhalten der Systeme mit der Grahameschen Theorie iiberein. Bei negativ polariziertem Bereich fiel die DoppelschichtskapazitLt der stlrken Elektrolytensysteme mit abnehmender Konzentration ab; das Ergebnis deutete an, dass die vollstindige Bildung der kompakten Doppelschicht in sehr verdiinnten LBsungen schwierig wird. Die Eigenschaften der Doppelschicht von CH,COOH und NHIOH Liisungen waren mit den-von st5irken Elektrolyten verglichen. Der Unterschied der differentiellen Kapazitst zwischen der schwachen und s&ken Elektrolytensysteme beim negativ polarizierten Bereich wurde auf den Ausdruck vom Dissoziationseffekt auf den schwachen Elektrolyten bedeutet.


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