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Double Isocyanide Insertion and C,C-Coupling Reaction of [(C 5 Me 4 )SiMe 2 (N-t-Bu)]ZrMe 2 . Structural Characterization of the Two 1,4-Diaza-5-zirconacyclopentene Ring Conformations for [(C 5 Me 4 )SiMe 2 (N-t-Bu)]Zr[N(R)C(Me)C(Me)N(R)] Complexes

✍ Scribed by Kloppenburg, Lioba; Petersen, Jeffrey L.


Book ID
127016998
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
333 KB
Volume
16
Category
Article
ISSN
0276-7333

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Evaluation of (η5-C5Me5)Hf(R)2[N(Et)C(Me
✍ Denis A. Kissounko; Yonghui Zhang; Matthew B. Harney; Lawrence R. Sita 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 122 KB 👁 1 views

## Abstract The dialkyl(monocyclopentadienyl)hafnium acetamidinates, Cp\*Hf(R)~2~[N(Et)C(Me)N(__t__‐Bu)] [Cp\*=η^5^‐C~5~Me~5~, R=Me (3a) and __i__‐Bu (3b)], were prepared through either ‘one–pot’ carbodiimide insertion or two‐step salt elimination protocols starting with commercially available Cp\*