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Unexpected P−Si or P−C Bond Cleavage in the Reaction of Li 2 [(C 5 Me 4 )SiMe 2 PR] (R = Cyclohexyl, 2,4,6-Me 3 C 6 H 2 ) and Li[(C 5 H 4 )CMe 2 PHR] (R = Ph, t Bu) with ZrCl 4 or [TiCl 3 (thf) 3 ]: Formation and Molecular Structure of the ansa -Metallocenes [{(η-C 5 Me 4 ) 2 SiMe 2 }ZrCl 2 ] and [{(η-C 5 H 4 ) 2 CMe 2 }MCl 2 ] (M = Ti, Zr) †

✍ Scribed by Koch, Thomas; Blaurock, Steffen; Somoza, Fernando B.; Voigt, Andreas; Kirmse, Reinhard; Hey-Hawkins, Evamarie

Book ID
126986811
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
186 KB
Volume
19
Category
Article
ISSN
0276-7333

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