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Double cycloaromatization of (Z,Z)-deca-3,7-diene-1,5,9-triyne: evidence for the intermediacy and diradical character of 2,6-didehydronaphthalene

✍ Scribed by Bharucha, Kamal N.; Marsh, Rebecca M.; Minto, Robert E.; Bergman, Robert G.


Book ID
126033205
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
281 KB
Volume
114
Category
Article
ISSN
0002-7863

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## Abstract In view of the significance of steric compression in the base‐catalyzed intramolecular cyclization of polycyclic olefinic alcohols, the standard enthalpies of formation of __anti__^9,10^‐10 __endo__‐hydroxytricyclo [4.2.1.1^2,5^]deca‐3,7‐dien‐9‐one **(1)** and 9‐oxatetracyclo [5.4.0.0^3