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Double asymmetric induction in the catalytic osmylation of some α,β-unsaturated octuronic acid derivatives

✍ Scribed by John S. Brimacombe; Graeme McDonald; M. Abdur Rahman


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
389 KB
Volume
205
Category
Article
ISSN
0008-6215

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Chiral dienolate chemistry in remote asy
✍ Katsuhiko Tomooka; Atsushi Nagasawa; Shih-Yi Wei; Takeshi Nakai 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 279 KB

The allylation of the dienolate derivedfrom the chiral a, p-orfl, ~unsaturated imidefollowed by the Cope rearmngement is shown to effect the net remote symmetric induction to create anew chirality of eitherconfiguration at the yposition in high 70 de. The utility of this qproach is shown in the mymm