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Double 1,3-dipolar cycloaddition of N-methyl Azomethine ylide to meta-Dinitrobenzene annelated with nitrogen aromatic heterocycles

✍ Scribed by Maxim A. Bastrakov; Alexey M. Starosotnikov; Sergey Yu. Pechenkin; Vadim V. Kachala; Ivan V. Glukhov; Svyatoslav A. Shevelev

Publisher: Journal of Heterocyclic Chemistry
Year: 2010
Tongue: English
Weight: 229 KB
Volume: 47
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.423

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✦ Synopsis

Abstract

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The 1,3‐dipolar cycloaddition of unstabilized azomethine ylide 1 with meta‐dinitrobenzene fused with nitrogen heterocycles affords the corresponding decahydropyrrolo[3,4‐e]isoindole cycloadducts in good yields. This is a first example of [3+2]‐cycloaddition of azomethine ylides to nitroarenes. J. Heterocyclic Chem., (2010).

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