Donorstabilisierte Aluminiumiodide: Ein Strukturvergleich
✍ Scribed by A. Ecker; H. Schnöckel
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- German
- Weight
- 82 KB
- Volume
- 624
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
✦ Synopsis
In order to compare aluminium-iodides in different oxidation states the following species containing identical donor ligands have been synthesized: Al 4 I 4 ´4 PEt 3 and AlI 3 ´2 PEt 3 . Their structural data are compared with those of the recently prepared Al 2 I 4 ´2 PEt 3 . In spite of different coordination numbers (4 and 5) the expected trends in the size of Al I , Al II and Al III and of their bonding to iodine and PEt 3 could be realized.
📜 SIMILAR VOLUMES
Durch die Strukturanalyse von H2C = C(PPh2), (1) konnte der konformationsbestimmende Effekt der C = C-Doppelbindung mit dem der P = C-Doppelbindung im Ylid Ph,P = C(PPh3, (A) verglichen werden. Die Kristallstrukturanalyse von 1 ergab, da8 im festen Zustand wirklich Bhnliche Konformationen der Ph2P-G