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Domino Michael Aldol and Domino Michael Mannich Reactions: Highly Stereoselective Synthesis of Functionalized Cyclohexanes

✍ Scribed by Christoph Schneider; Oliver Reese

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
97 KB
Volume
39
Category
Article
ISSN
0044-8249

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## Abstract The domino Mannich/aza‐Michael reaction of γ‐malonate‐substituted α,β‐unsaturated esters with __N__‐protected arylaldimines has been achieved. Catalyzed by bifunctional thioureas, 2,5‐__cis__‐configured polysubstituted pyrrolidines are obtained in good to excellent yields (76–99%), enan