Structure and Bonding of Low-Valent (Fis
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Sergei F. Vyboishchikov; Gernot Frenking
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Article
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1998
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John Wiley and Sons
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English
⚖ 266 KB
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Quantum mechanical ab initio calculations are reported at the MP2 level of theory with effective core potentials for the heavy atoms of the low-valent carbene complexes [(CO) 5 WCH 2 ] (1), [(CO) 5 WCF 2 ] (2), [(CO) 5 WCHF] (3), and [(CO) 5 WCH-(OH)] (4), and for the high-valent carbene complexes [