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Does the basicity of xenon-129 affect its NMR chemical shift?

✍ Scribed by Arnett, Edward M.; Wernett, Patrick C.


Book ID
126191767
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
193 KB
Volume
115
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


129Xe NMR of xenon adsorbed on zeolites:
✍ J. Demarquay; J. Fraissard πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 428 KB

experiments we have determined values of the mean free path 1 of xenon adsorbed on various zeolites. We deduce from them the dependence of the chemical shift S on 1. It is now possible to determine the dimensions of any cavity in which xenon can be adsorbed.

The relation betwen the 129Xe NMR chemic
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The adsorption isotherms and lz9Xe NMR chemical shifts of xenon in the voids of zeolite Y with O%, 53%, 75%, and 95% exchange of copper (II) for sodium ions were determined. With increasing copper content the shifts go uptield. The local chemical shifts of xenon at a crystallographic SII site with a