𝔖 Bobbio Scriptorium
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d,l-Desoxy-chloromycetin

✍ Scribed by K. Eiter; E. Sackl


Book ID
112429065
Publisher
Springer Vienna
Year
1952
Tongue
English
Weight
773 KB
Volume
83
Category
Article
ISSN
0026-9247

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l-Desoxy-chloromycetin
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A Convenient Route to 3′‐Deoxy‐α‐L‐ and 3′‐Deoxy‐β‐D‐apionucleosides The cyclic thionocarbonate 3, easily available in three steps from 3′‐__O__‐benzoyl‐2,3‐__O__‐isopropylidene‐D‐apio‐β‐D‐furanose (1), is deoxygenated with __n__‐Bu~3~SnH to yield the 3′‐deoxy epimers 4 [methyl 3‐C‐(benzoyloxymethy