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Diverse products accessible via [2 + 2] photocycloadditions of 3-aminocyclopentenones

✍ Scribed by Roupany, Andrew J. A.; Baker, James R.


Book ID
120456810
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
343 KB
Volume
3
Category
Article
ISSN
2046-2069

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## Abstract Irradiation of an aryl group with a silyl tethered alkene yields a tetracyclic 2‐silaoxane with high regiose‐lectivity. The multicyclic structure has been further modified to give an unstable tricyclic diol. Photocycloaddition between cyclopentene and phenylcyclopropane gave a single ma

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The (2 + 21 photocycloaddition of 2-(trimethylsilyloxy)-1,3-butadiene to a number of 2-cycloalkenones proved to be quite a general reaction leading to good yields of the cycloadducts (Table ). This finding is surprising since dienes, in general, are better known as quenchers of enone triplets rather