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ChemInform Abstract: Synthesis of 2-Silaoxane via 1,3-Photocycloaddition.

✍ Scribed by Suhail Bahu; Steven A. Fleming; Brad Nilsson; Tim Turner

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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Synthesis of 2-silaoxane via 1,3- photoc
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## Abstract Irradiation of an aryl group with a silyl tethered alkene yields a tetracyclic 2‐silaoxane with high regiose‐lectivity. The multicyclic structure has been further modified to give an unstable tricyclic diol. Photocycloaddition between cyclopentene and phenylcyclopropane gave a single ma

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