Divergent synthesis of segmented carbosilane dendrimers
✍ Scribed by E. A. Rebrov; G. M. Ignat’eva; A. I. Lysachkov; N. V. Demchenko; A. M. Muzafarov
- Book ID
- 110197243
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2007
- Tongue
- English
- Weight
- 367 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0965-545X
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A divergent route for the synthesis of carbosilane wedges containing either a bromine or amine as a focal point has been developed lot the construction of core functionalised dendrimers; carbosilane dendrimers up to the third generation containing a 1,3,5benzene triamide core capable of binding gues
The new organosilane 4-triallylsilylphenol (1) can be synthesised in high yield via two routes using either 4-bromophenol or its silyl-group protected derivative as starting materials. Compound 1 can be used in the divergent or convergent synthesis of carbosilane dendrimers or conversely as a readil