Highly stereoselective synthesis of eryt
✍
Tadashi Nakata; Tadasu Tanaka; Takeshi Oishi
📂
Article
📅
1981
🏛
Elsevier Science
🌐
French
⚖ 253 KB
Erythro-a, B-epoxy alcohols were prepared in high stereoselectivity by zinc borohydride reduction of the corresponding a, B-epoxy ketones regardless of the substituents on the epoxide ring. Epoxidation of the ally1 alcohols (L) with tert-butyl hydroperoxide catalyzed by VO(acac)2 was reported to giv