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Divergent electrochemical carboxylation of vinyl triflates: new electrochemical synthesis of phenyl-substituted α,β-unsaturated carboxylic acids and aliphatic β-keto carboxylic acids

✍ Scribed by Hisanori Senboku; Yusuke Fujimura; Hisato Kamekawa; Masao Tokuda

Book ID
108317516
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
111 KB
Volume
45
Category
Article
ISSN
0013-4686

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New Electrochemical Carboxylation of Vinyl Triflates. Synthesis of β-Keto Carboxylic Acids. -Electrolytic reduction of cyclic vinyl triflates (I) in the presence of carbon dioxide (II) results in the formation of β-keto carboxylic acids (III) in moderate to good yields. -(KAMEKAWA,