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New electrochemical carboxylation of vinyl triflates. Synthesis of β-keto carboxylic acids

✍ Scribed by Hisato Kamekawa; Hisanori Senboku; Masao Tokuda

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
202 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Electrochemical reduction of alicydic vinyl triflates (la -1 e) in a DMF solution containing 0.1 M Be4NIF 4 under an atmospheric pressure of cmbon dioxide with a platinum cathode and a magnesium anode resulted in the cleavage of an oxygen-sulfer bond of 1 to give the corresponding 15-keto cmboxylic acids (2n-2e) in yields of 28-77%.

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