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Divalent Palladium and Platinum Complexes Containing Rigid Bidentate Nitrogen Ligands and Electrochemistry of the Palladium Complexes 1

✍ Scribed by van Asselt, Rob; Elsevier, Cornelis J.; Amatore, Christian; Jutand, Anny


Book ID
120255774
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
442 KB
Volume
16
Category
Article
ISSN
0276-7333

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The reaction of 1,2-diamines la-c with Ph3PBr2 in the presence of triethylamine gives rise to the corresponding diphosphonium salts 2a-c in good yields. Treatment of these salts with NaH at room temperature in CH,Cl, affords the diiminophosphoranes 3a-c in near quantitative yields. Derivatives 3a,b