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Disulfonimide-Catalyzed Asymmetric Vinylogous and Bisvinylogous Mukaiyama Aldol Reactions

✍ Scribed by Lars Ratjen; Dr. Pilar García-García; Frank Lay; Dr. Michael Edmund Beck; Prof. Dr. Benjamin List

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
436 KB
Volume
50
Category
Article
ISSN
0044-8249

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C1-Symmetric Aminosulfoximines in Copper-Catalyzed Asymmetric Vinylogous Mukaiyama Aldol Reactions
✍ Marcus Frings; Iuliana Atodiresei; Yutian Wang; Jan Runsink; Gerhard Raabe; Cars 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 376 KB 👁 1 views

## Abstract Vinylogous Mukaiyama‐type aldol reactions have been catalyzed by a combination of Cu(OTf)~2~ and readily available __C__~1~‐symmetric aminosulfoximines. After a fine‐tuning of the reaction conditions and an optimization of the modularly assembled ligand structure, high stereoselectiviti