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Distinguishing Electronic and Vibronic Coherence in 2D Spectra by Their Temperature Dependence

✍ Scribed by Perlík, Václav; Lincoln, Craig; Šanda, František; Hauer, Jürgen

Book ID
127044701
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
834 KB
Volume
5
Category
Article
ISSN
1948-7185

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✍ Thomas Luxbacher; Harald P. Fritzer; Colin D. Flint 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 341 KB

The 3H4~3P o transition in the absorption spectra of Pr 3+ in the hexachloroelpasolites Cs2NaPrxY~\_xCl6 (X=0.1 to x= 1 ) have been measured from 300 to 10 K. The electronic spectra are dominated by electric-dipole allowed vibronic origins enabled by Herzberg-Teller coupling. The two odd parity vibr