✦ LIBER ✦

Distinctive chemo- and stereo-selective reactions of [Fe(CO)2Cp]+ and [AuPPh3+ with the anionic thioketene complex, [W(CO)5&[;C(OEt)(Ph)C(Ph)=C=S&];]−. Crystal structures of Z-[W(CO)5&[;C(SFe[CO]2Cp)C(Ph)=C(OEt)Ph&];] and E-[W(CO)5&[;S=C(AuPPh3)C(Ph)=C(OEt)Ph&];]

✍ Scribed by Helgard G. Raubenheimer; Gert J. Kruger; Charles F. Marais; Johannes T.Z. Hattingh; Lorna Linford; Petrus H. van Rooyen

Book ID: 107811285
Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 822 KB
Volume: 355
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(88)89035-1

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reactivity of the Metallophosphaalkene [

Reactivity of the Metallophosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] towards Alkyl-, Aryl-, Alkenyl-, and Alkynylcarbene Complexes [(CO)5M=C(OEt)R] (M=Cr, W; R=CH3, Ph, CH=CHPh, C≡CPh)

✍ Lothar Weber; Beate Quasdorff; Hans-Georg Stammler; Beate Neumann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB 👁 1 views

Syntheses of acyloxy carbene complexes M

Syntheses of acyloxy carbene complexes M(SnPh3)(CO) n {?C(OCOR)Ph}(?-C5H5)(M = Mo,W, n= 2, R = Me; M = Fe, Ru, n= 1, R = Me, Ph, But) and X-ray crystal structures of Fe(SnPh3){CO){?C(OCOR)Ph}(?-C5H5)(R = Me, Ph)

✍ Adams, Harry; Maloney, Colin A.; Muir, Jayne E.; Walters, Stephen J.; Winter, Ma 📂 Article 📅 1995 🏛 The Royal Society of Chemistry 🌐 English ⚖ 298 KB

Regioselective Addition of Mixed-Chalcog

Regioselective Addition of Mixed-Chalcogenide Iron Carbonyl Clusters Fe 2 (CO) 6 (μ-EE‘) (E ≠ E‘, E, E‘ = S, Se, Te) to a Carbon−Carbon Triple Bond Activated by a Metal Carbene Fragment. Structural Characterization of New Trimetallic Adducts Fe 2 (CO) 6 {μ-SC(Ph)C(Te)[(OEt)CCr(CO) 5 ]}, Fe 2 (CO) 6 - {μ-SC(Ph)C(Se)[(OEt)CW(CO) 5 ]}, and Fe 2 (CO) 6 {μ-SeC(Ph)C(Te)[(OEt)CW(CO) 5 ]}

✍ Mathur, Pradeep; Ghosh, Sundargopal; Sarkar, Amitabha; Satyanarayana, C. V. V.; 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 160 KB

Insertion reactions of [Pt(PPh3)2] fragm

Insertion reactions of [Pt(PPh3)2] fragments into the four-membered ring complex [W(CO)5PPhC(OEt)CPhCHPh]. Crystal and molecular structures of [Pt(dppe)PPh(W(CO)5)C(OEt)CPhCHPh] and [Pt(PPh3)2((W(CO)5)PhPC(OEt)CPhCHPh)(η2-PC))]

✍ Florence A. Ajulu; Salih S. Al-Juaid; Duncan Carmichael; Peter B. Hitchcock; Moh 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 283 KB

Preparation of (.eta.-C5H5)W(CO)2(PPh3)S

Preparation of (.eta.-C5H5)W(CO)2(PPh3)SR and the insertion of carbon disulfide to give the thioxanthates (.eta.-C5H5)W(CO)2S2CSR (R = CHMe2, CH2Ph, and 4-C6H4Me). Crystal structure of (.eta.-C5H5)W(CO)2S2CSCH2Ph

✍ Shaver, Alan; Lum, Bernadette Soo; Bird, Peter; Arnold, Kevin 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 689 KB

Fragmentation reactions ofN-sulfinylanil

Fragmentation reactions ofN-sulfinylaniline PhNSO by the dinuclear complex [Fe2(CO)7{μ-C(R)C(NEt2)}]: Nitrene and sulfur insertions into iron carbene bonds. Synthesis and x-ray structures of [Fe2(CO)6{μ-N(Ph)C(NEt2)C(Me)S}] [Fe2(CO)6{μ-N(Ph)C(NEt2)C(Ph)S}] · 0.5C6H14and [Fe2(CO)6{μ-C(C3H5)C(NEt2)N(Ph)SO}] · 0.5CH2Cl2

✍ Jean-Claude Daran; Bernd Heim; Yves Jeannin 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 912 KB