Distinct Complex Precipitating from Racemic Solution of Poly(β-benzyl l -aspartate) and Poly(β-benzyl d -aspartate)
✍ Scribed by Sakajiri, Kou-ichi; Kawasaki, Ei-ichi; Watanabe, Junji
- Book ID
- 126068537
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 78 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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As the t,emperatiire of solid poly(&benzyl-L-aspart.ate) (PRLA), (CO . N H . C H .-CH2COOCHrCsH,),, in the a-helical form is raised froml.iO"C, the line width and second moment of the proton magnetic resonance (PMR ) sigiial decrease in stages riiitil the conformational transition to the w-helix occ
Poly(P-benzyl-L-aspartate) (PBLA) is an unusual polypeptide, which is capable of going into four different conformations, namely, left-handed a helix, right-handed a helix, o helix, and fi pleated sheet. The present work is a complete study of normal modes and their dispersion in the unusual left-ha