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Distinct Complex Precipitating from Racemic Solution of Poly(β-benzyl l -aspartate) and Poly(β-benzyl d -aspartate)

✍ Scribed by Sakajiri, Kou-ichi; Kawasaki, Ei-ichi; Watanabe, Junji


Book ID
126068537
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
78 KB
Volume
34
Category
Article
ISSN
0024-9297

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📜 SIMILAR VOLUMES


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✍ F. Happey; D. W. Jones; B. M. Watsox 📂 Article 📅 1971 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 494 KB 👁 1 views

As the t,emperatiire of solid poly(&benzyl-L-aspart.ate) (PRLA), (CO . N H . C H .-CH2COOCHrCsH,),, in the a-helical form is raised froml.iO"C, the line width and second moment of the proton magnetic resonance (PMR ) sigiial decrease in stages riiitil the conformational transition to the w-helix occ

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Poly(P-benzyl-L-aspartate) (PBLA) is an unusual polypeptide, which is capable of going into four different conformations, namely, left-handed a helix, right-handed a helix, o helix, and fi pleated sheet. The present work is a complete study of normal modes and their dispersion in the unusual left-ha