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Dissymmetric Non-conjugated Chromophores. Optical Rotatory Dispersion of Bicyclo[2.2.1]hept-5-en-2-one and Bicyclo[2.2.2]oct-5-en-2-one

✍ Scribed by Mislow, Kurt.; Berger, Joel G.


Book ID
126063368
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
726 KB
Volume
84
Category
Article
ISSN
0002-7863

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Swrmary: A new and highly stereoselective palladium-catalyzed synthesis is reported, based on two subsequent insertions of the bicycloE.2.gheptene system into an aryl or vinylpalladium bond, formed in situ from aryl or vinyl bromides. Recent papers on the synthesis of prostaglandin endoperoxide ana