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Dissymmetric arsine complexes. An analysis of the circular dichroism spectra of chiral diarsine complexes of cobalt(III)

โœ Scribed by Jackson, W. G.; McLaren, J. W.; Bosnich, B.

Book ID
126812480
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
479 KB
Volume
22
Category
Article
ISSN
0020-1669

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Circular dichroism of cobalt(III) comple
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โœ Lucjan Dubicki; James Ferguson; Rodney J. Geue; Alan M. Sargeson ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 347 KB

The smgle crystal az~al CD of three Co(ii1) complekes has been measured between 295 and 9 K. For A-Co (sepulchrate) (NO313 the rotatlonal strength R('Tl(E) -lA1) decreases from =l I X lOdo c.g.s. umts at 295 K to ~0 at 80 K. The main features of the smgle crystal CD spectra can be evplamed by a Stai