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Dissymetrisation de la molecule de glyoxal: II. Action des organometalliques sur l'acetoxy-1 triethoxy-1,2,2 ethane

✍ Scribed by A. Stambouli; R. Amouroux; F. Chastrette; M. Chastrette; G. Mattioda; A. Blanc

Book ID
103222820
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
427 KB
Volume
307
Category
Article
ISSN
0022-328X

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Dissymetrisation de la molecule du glyox
Dissymetrisation de la molecule du glyoxal 1-synthese et reactivite de L'acetoxy-1 triethoxy-1,2,2 ethane
✍ A Stambouli; F Chastrette; R Amouroux; M Chastrette; G Mattioda; A Blanc 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 281 KB

Acgtoxy-1 trie'thoxy-1,2,2 ethane, a dissymetric derivative of glyoxal, is prepared and reacted with various bases and nucleophiles, as amines, cyanotrimethylsilane, organometallic and WITTIC reagents. Various acetals are obtained, leading to a-fonctionalized aldehydes. Premier terme des dialdehydes