✦ LIBER ✦

Dissociative electron transfer. New tests of the theory in the electrochemical and homogeneous reduction of alkyl halides

✍ Scribed by Saveant, Jean Michel

Book ID: 127313876
Publisher: American Chemical Society
Year: 1992
Tongue: English
Weight: 992 KB
Volume: 114
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00052a065

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A simple model for the kinetics of disso

A simple model for the kinetics of dissociative electron transfer in polar solvents. Application to the homogeneous and heterogeneous reduction of alkyl halides

✍ Saveant, Jean Michel 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 831 KB

Dissociative electron transfer. Autocata

Dissociative electron transfer. Autocatalysis and kinetic characteristics of the electrochemical reductive cleavage of the carbon halogen bond in alkyl halides giving rise to stable radicals and carbanions

✍ Andrieux, Claude P.; Merz, Andreas; Saveant, Jean Michel 📂 Article 📅 1985 🏛 American Chemical Society 🌐 English ⚖ 911 KB

Concerning the reduction of alkyl halide

Concerning the reduction of alkyl halides by LiAlH4 evidence that AlH3 produced in situ is the one electron transfer agent.

✍ E.C. Ashby; R.N. DePriest; T.N. Pham 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The reduction of lo and 2' alkyl iodides by LiA1H4.has been shown to involve a radical intermediate formed by the reaction of the alkyl iodide with the AlH3 and LiI produced in situ in conjunction with LiAlH4 rather than by LiAlH4 alone, as evidenced by cyclized products in the reduction of 6-iodo-1

Cyclopropyl halides. Electron transfer i

Cyclopropyl halides. Electron transfer in the lithium aluminum hydride reduction of gemdibromo and monobromocyclopropanes.

✍ Michael A. McKinney; Steve W. Anderson; Michael Keyes; Ronald Schmidt 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 225 KB

Passage from Concerted to Stepwise Disso

Passage from Concerted to Stepwise Dissociative Electron Transfer as a Function of the Molecular Structure and of the Energy of the Incoming Electron. Electrochemical Reduction of Aryldialkyl Sulfonium Cations

✍ Andrieux, Claude P.; Robert, Marc; Saeva, Franklin D.; Saveant, J.-M. 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 939 KB

Homogeneous Electron Transfer Catalysis

Homogeneous Electron Transfer Catalysis of the Electrochemical Reduction of Carbon Dioxide. Do Aromatic Anion Radicals React in an Outer-Sphere Manner?

✍ Gennaro, Armando; Isse, Abdirisak A.; Savéant, Jean-Michel; Severin, Maria-Gabri 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 231 KB