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Dissociation dynamics of energy-selected hexamethyldisilane ions and the heats of formation of trimethylsilyl(1+) ion ((CH3)3Si+) and trimethylsilyl radical ((CH3)3Si)

✍ Scribed by Szepes, Laszlo; Baer, Tomas


Book ID
127026401
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
752 KB
Volume
106
Category
Article
ISSN
0002-7863

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A photoionization study of the ion-neutr
✍ John C. Traeger; Charles E. Hudson; David J. McAdoo πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 910 KB

## Photoionization mass spectrometry was used to investigate the dynamics of ion-neutral complex-mediated dissociations of the Iz-pentane ion (1). Reinterpretation of previous data demonstrates that a fraction of ions 1 isomerizes to the 2-methylbutane ion (2) through the complex [CHaCH+CHa'CH,CH,