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Heats of formation of the ions BrKr+ and CH3Kr+

โœ Scribed by H.P. Watkins; W.S. Koski

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
194 KB
Volume
77
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES

An examination of the heats of formation
An examination of the heats of formation for CH3CO and CF3CO radicals
โœ J.S. Francisco; N.J. Abersold ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 399 KB

The heats of formation for CHsCO and CFsCO molecules have been determined using ab initio molecular orbital calculations from isodesmic schemes. The heat of formation for CHJCO has been calculated as -4.2 +2 kcal mol-', which is in good agreement with experiment and that for CF,CO as -139.9 f 2 kcal

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The proton affinity of ketene and the heat of formation of CH3CO+
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The equilibrium for proton transfer involving acetone and ketene (CH$OCHsH++ CH2CO -CH$O++ CHsCOCH3) has been studied in a pulsed ion cyclotron resonance spectrometer. Vtiues of 193.6 r I and 194.1 c 1 kcal/mole (1 kcal/mole = 4.18 kjoules) are obtained for the proton affinities of acetone and keten

Heats of formation of multi-substituted
Heats of formation of multi-substituted positive ions of organic species
โœ Yu-Ran Luo; Yan An; John L. Holmes ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 586 KB

The difference (AAf W ) between heats of formation of many multi-substituted odd-and even-electron positive ions can be described by a linear equation: Ah, ff = A + Bm, where rn is the number of substituents or ligands, relative to the unsubstituted reference ion, and m = 1, 2 or 3; A and B are the