Structural properties of uranyl cations in acidic aqueous perchlorate and triflate solutions were investigated using uranium L III -edge extended X-ray absorption fine-structure spectroscopy (EXAFS) in conjunction with quantum mechanical calculations of gas-phase model complexes. EXAFS spectra were
✦ LIBER ✦
Disproportionation and ECE mechanisms—II. Reduction of the uranyl cation in perchloric acid
✍ Scribed by M. Mastragostino; J.M. Saveant
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 751 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0013-4686
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## Abstract The Ce(IV) oxidation of the five‐, six‐, and seven‐membered ring α‐hydroxycycloalkanecarboxylic (C5, C6, and C7) acids to the corresponding cyclic ketones has been studied in acidic perchlorate media. The data may be interpreted in terms of a mechanism which involves fast preequilibrium