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Dispersed Fluorescence Spectroscopy of the ZnC2H5Free Radical

✍ Scribed by Simon J. Pooley; Andrew M. Ellis

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 146 KB
Volume: 185
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1997.7361

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✦ Synopsis

Dispersed fluorescence spectra of the zinc monoethyl radical are presented. These have allowed vibrational frequencies of several modes in the ground electronic state of this molecule to be determined for the first time. In particular, substantial activity in both the Zn-C stretch and the Zn-C-C bend has been observed, with the frequencies for these modes being deduced as 387 and 180 cm 01 , respectively. With the aid of the dispersed fluorescence data it has also proved possible to make reasonable assignments for several bands in the excitation spectrum. ZnC 2 H 5 was prepared in these experiments by a dc electrical discharge through an argon/diethyl zinc mixture in a supersonic nozzle. ᭧ 1997

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