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Discrete Supramolecular Donor–Acceptor Complexes

✍ Scribed by S. Shankara Gayathri; Mateusz Wielopolski; Emilio M. Pérez; Gustavo Fernández; Luis Sánchez; Rafael Viruela; Enrique Ortí; Dirk M. Guldi; Nazario Martín

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
631 KB
Volume
48
Category
Article
ISSN
0044-8249

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✍ Itamar Willner; Sharon Marx-tibbon; Shmuel Cohen; Yoav Eichen; Menachem Kaftori 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB

## trans-4,4Ј(N,NЈ-Dimethylpyridinium)ethylene [trans-(1)] and cis-4,4Ј(N,NЈ-dimethylpyridinium)ethylene [cis -1] form with 2,7-dichlorofluorescein [DCF 2 Ϫ , (2)] donor-acceptor complexes of 1:1 stoichiometry [K(trans-1) = 14 000 M Ϫ 1 and K(cis-1) = 300 M Ϫ 1 in water]. The lower affinity of cis

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The 1 : 1 electron donor-acceptor complexes of 2,4-dinitrophenol with lipids such as egg lecithin, synthetic lecithin and oxidized cholesterol have been studied spectrophotometrically in carbon tetrachloride solution. The charge-transfer absorption band has been found in the near ultraviolet for eac