Discrete simulation of cenospheric coal-char combustion
β Scribed by Ranajit Sahu; Richard C. Flagan; George R. Gavalas
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 582 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0010-2180
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β¦ Synopsis
A phenomenological model of structural transformations during pulverized coal char combustion is presented. The random geometry of the voids is modeled realistically by means of a random assemblage of spheres in a spherical particle. Pore counectedn~s and growth are accounted for as the combustion proceeds. The percolation behavior of the void space is dramatically demonstrated. The effects of different initial void fractions and of the random nature of the structure itself, at a given initial void fraction, are shown. This sheds some light on our ability to realistically model the solid. The limitation of shrinking core models of combustion of cenospheric chars are demonstrated. In this initial application, the model is limited to isothermal combustion with no diffusional limitations.
π SIMILAR VOLUMES
A mathematical model is developed that represents a first approximation of the dynamics of the coal char combustion. The model determines a range of particle sizes and gas temperatures where oscillation can occur and propagating spherical waves surround the particle. It is also possible to compute t
Combustion rate measurements of Loy Yang brown coal char particles (88 #m median size) over the temperature range 940-1420 K yielded a chemical rate coefficient Re, expressed as Re= 12.6 expl-68.3/(RTp)] kg/m2s (kPa 02) Β°.4. Particle size and density decreased with burn off, but in an unusual manne
## Abstract The physical and chemical characteristics that influence the conversion of fuel nitrogen to nitrogen oxides during coal char combustion were theoretically examined by using a simplified model in which nitric oxide is an intermediate product between fuel nitrogen and N~2~. It was found
time is the same as that corresponding to pore diffusion control (Equation ( )). If the evolution of surface area can be described by: S/S,=(l-f)"3 (6) the resulting equation for the conversion coincides with that for film-diffusion control (Equation ( )). Therefore, it is concluded that much care