Dirhodium(II)-Catalyzed C—H Insertion on α-Diazo-α-phosphono-acetamides in an Ionic Liquid.
✍ Scribed by Pedro M. P. Gois; Carlos A. M. Afonso
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 127 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy