Dirhodium(II)-catalyzed carbonyl ylide generation. Stereoelectronic control in dioxolane formation
β Scribed by M. P. Doyle; D. C. Forbes; K. R. Xavier
- Book ID
- 105597733
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 356 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Enantioselective 1,3-dipolar cycloaddition of the ester-carbonyl ylides derived from methyl 2-(diazoacetyl)benzoate and 3-(diazoacetyl)-2-naphthoate with dipolarophiles has been eected with the aid of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate], aording cycloadducts in up to 93% ee.
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