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Directing Effects of Tethered Alkenes in Nickel-Catalyzed Coupling Reactions of 1,6-Enynes and Aldehydes.

✍ Scribed by Ryan M. Moslin; Karen M. Miller; Timothy F. Jamison

Publisher
John Wiley and Sons
Year
2006
Weight
35 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract The more electron‐withdrawing the N‐protecting group and the alkene substituent, the slower is the reaction rate of the cycloisomerization of 1,6‐enynes to yield bicyclic products (II) and (IV).