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Directed Regio- and Stereoselective Nickel-Catalyzed Addition of Alkyl Grignard Reagents to Allylic Ethers

✍ Scribed by Didiuk, Mary T.; Morken, James P.; Hoveyda, Amir H.


Book ID
111688902
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
268 KB
Volume
117
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Phosphine-Directed
✍ M. T. DIDIUK; J. P. MORKEN; A. H. HOVEYDA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 39 KB πŸ‘ 2 views

Phosphine-Directed Stereo-and Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers. -In the presence of a properly positioned internal Lewis base like a phosphine unit various acyclic and cyclic allylic ethers are regio-and stereoselectively methylated or phenylated. Under