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Directed oxidative cyclization of 5-hydroxyalkenes with rhenium oxide

โœ Scribed by Robert M. Kennedy; Suhan Tang

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
280 KB
Volume
33
Category
Article
ISSN
0040-4039

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Treatment of the tertiary cyclooctenolz with lead tetraacetate or with chromium(V1) reagents results in transannular oxidative cyclization to 8-functionalized bicyclic ethers, and the selectivity between the oxabicyclo[3.3.l]nonane and the oxabicyclo[4.2.l]nonane skeleton depends on the nature of th