## Methoxy-substituted benzenes 1 are oxidized with aqueous hydrogen peroxide catalyzed by methyltrioxorhenium( VII) in acetic acid to yield the p-benzoquinones 3 in moderate yields. An intermediary diperoxo rhenium(W) complex rather than peracetic acid is the dominating oxidizing species, since o
Regioselective oxidative cyclization of hydroxyalkenes to tetrahydrofurans catalyzed by methyltrioxorhenium
β Scribed by Haisong Tan; James H. Espenson
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 139 KB
- Volume
- 152
- Category
- Article
- ISSN
- 1381-1169
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π SIMILAR VOLUMES
OsO4 catalyzes the oxidative cyclization of the 1,5-dienes geranyl acetate (1) and neryl acetate (2) to the cis-2,5-bis(hydroxymethyl)tetrahydrofurans 3 and 4 respectively, in the presence of NalO4 as cooxidant in DMF. The reaction is stereospecific and proceeds with the sequential syn addition to b
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v