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Direct Visualization of “Coagulative Nucleation” in Surfactant-Free Emulsion Polymerization

✍ Scribed by Dobrowolska, Marta E.; van Esch, Jan H.; Koper, Ger J. M.


Book ID
121309022
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
786 KB
Volume
29
Category
Article
ISSN
0743-7463

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Based on the coagulative particle nucleation mechanism, a two-step model has been developed for the semi-batch surfactant-free emulsion polymerization of butyl acrylate, or butyl acrylate in the presence of a small amount of acrylic acid. During Stage 1, precursor particles are Ðrst formed by phase