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Direct Use of Allylic Alcohols for Platinum-Catalyzed Monoallylation of Amines

✍ Scribed by Utsunomiya, Masaru; Miyamoto, Yoshiki; Ipposhi, Junji; Ohshima, Takashi; Mashima, Kazushi


Book ID
127059379
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
139 KB
Volume
9
Category
Article
ISSN
1523-7060

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Direct palladium-catalyzed selective mon
✍ Shyh-Chyun Yang; Chia-Lin Yu; Yan-Chiu Tsai πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 195 KB

N-Allylation of anilines using allylic alcohols directly to give monoallylic anilines selectively in high yields has been realized by employing palladium acetateΒ±triphenylphosphine as the catalyst. Palladiumcatalyzed one-pot cyclization of 2-aminophenols with 2-butene-1,4-diol leads to 3,4-dihydro-2