𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Direct synthesis of β-mannosides. Synthesis of β-D-xyl-(1→2)-β-D-man-(1→4)-α-D-Glc-OMe: A trisaccharide component of the Hyriopsis schlegelii glycosphingolipid. Formation of an orthoester from a xylopyranosyl sulfoxide

✍ Scribed by David Crich; Zongmin Dai


Book ID
108379209
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
818 KB
Volume
55
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Direct synthesis of β-d-Xyl-(1→2)-β-d-Ma
✍ David Crich; Zongmin Dai 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 179 KB

Almtraet. A synthesis of the target trisaccharide is described in which the key l~,-mannosylation is achieved in high yield and selectivity through reaction of the sulfoxide 7 with acceptor 8, meAiated with triflic anhydride. The xylosylation was best coudueted using trihenzoyl xylopyranosyl bromid