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ChemInform Abstract: Direct Synthesis of β-Mannosides. Synthesis of β-D-Xyl-(1→2)-β-D-Man-(1→4)-α-D-Glc-OMe: A Trisaccharide Component of the Hyriopsis schlegelii Glycosphingolipid. Formation of an Orthoester from a Xylopyranosyl Sulfoxide.

✍ Scribed by David Crich; Zongmin Dai


Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of Protec
✍ J. A. L. M. VAN DORST; A. F. VOSKAMP; J. P. KAMERLING; J. F. G. VLIEGENTHART 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Synthesis of Protected Hexp-(1 → 4)-β-D-GlcpNAc-(1 → 2)-α-D-Manp-(1 → O)(CH2)7CH3 Sequences (Hex: β-D-Glc, 4-deoxy-4fluoro-β-D-Gal, or 4-deoxy-β-D-Gal) Using a Glc-GlcNPhth Donor, Eventually Fluorinated or Deoxygenated at the Oligosaccharide Level. -The title trisaccharide derivatives are prepared