Direct Synthesis of Tris(chlorosilyl)methanes Containing Si−H Bonds
✍ Scribed by Han, Joon Soo; Yeon, Seung Ho; Yoo, Bok Ryul; Jung, Il Nam
- Book ID
- 127347968
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 117 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0276-7333
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## Abstract Tris(dimethylsilyl)methane, (HMe~2~Si)CH, reacts with __n__‐propyl, iso‐propyl, __n__‐butyl, s‐butyl, iso‐butyl, __n__‐pentyl, s‐pentyl, __n__‐hexyl alcohol, and phenol in the presence of chloroplatinic acid (H~2~PtCl~6~ċ6H~2~O) in air to give products (ROMe~2~Si)~3~CH (where R is __n__
Silicon-29 spin-lattice relaxation times and 29Si-(1H} nuclear Overhauser enhancements are reported for five trialkylsilanes and for sym-tetramethyldisiloxane, all of which contain a direct Si-H bond. Relaxation rate contributions from (Si, H) dipolar interactions and from other mechanisms are evalu