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Direct synthesis of bis(silyl)methanes containing silicon-hydrogen bonds

โœ Scribed by Jung, Il Nam; Yeon, Seung Ho; Han, Joon Soo


Book ID
126968940
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
356 KB
Volume
12
Category
Article
ISSN
0276-7333

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โœ Masahiro Murakami; Hideaki Oike; Mitsuru Sugawara; Michinori Suginome; Yoshihiko ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 1008 KB

Abstmct: A new strategy for the stereoselective synthesis of 1.2.4~uiols has been developed. An alkyne tethered to a disilanyl group, upon treatment with palladium acetate and tert-alkyl isocyanide, furnished an exocyclic bii-silylated olefin. Subsequent hydrogenation took place from the less-hinder