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Direct synthesis of thioethers from sulfonyl chlorides and activated alcohols

โœ Scribed by Michael T Martin; Alford M Thomas; Douglas G York

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
138 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

An efficient, safe one-pot synthesis of thioethers from aromatic sulfonyl chlorides and activated alcohols has been developed under non-aqueous conditions.

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Synthesis of [35S]aryl sulfonyl chloride
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โœ Michael A. Wallace; Conrad E. Raab; Dennis C. Dean; David G. Melillo ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 111 KB

A new synthetic methodology that captures electrophilic 35 S 8 with aryl Grignard reagents or lithiates provides entry to a wide variety of [ 35 S]aryl sulfonyl chlorides upon oxidation and chlorination.