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Direct Synthesis of Protected Arylacetaldehydes by Palladium-Tetraphosphine-Catalyzed Arylation of Ethyleneglycol Vinylether.

✍ Scribed by Isabelle Kondolff; Henri Doucet; Maurice Santelli

Publisher
John Wiley and Sons
Year
2004
Weight
23 KB
Volume
35
Category
Article
ISSN
0931-7597

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Direct Synthesis of Protected Arylacetal
Direct Synthesis of Protected Arylacetaldehydes by Tetrakis(phosphane)palladium-Catalyzed Arylation of Ethyleneglycol Vinyl Ether.
✍ Isabelle Kondolff; Henri Doucet; Maurice Santelli πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 17 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Direct Synthesis of Protected Arylacetal
Direct Synthesis of Protected Arylacetaldehydes by Tetrakis(phosphane)palladium-Catalyzed Arylation of Ethyleneglycol Vinyl Ether
✍ Isabelle Kondolff; Henri Doucet; Maurice Santelli πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 179 KB

## Abstract A range of aryl bromides undergo Heck reaction with ethylene glycol vinyl ether, in the presence of [PdCl(C~3~H~5~)]~2~/__cis__,__cis__,__cis__‐1,2,3,4‐tetrakis[(diphenylphosphanyl)methyl]cyclopentane as catalyst, to give regioselectively protected arylacetaldehydes in good yields. The