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Direct studies of 1,1-diazenes. Syntheses, infrared and electronic spectra, and kinetics of the thermal decomposition of N-(2,2,6,6-tetramethylpiperidyl)nitrene and N-(2,2,5,5-tetramethylpyrrolidyl)nitrene

โœ Scribed by Hinsberg, William D.; Schultz, Peter G.; Dervan, Peter B.


Book ID
126773418
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
1007 KB
Volume
104
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Synthesis, Thermal
โœ A. RAHTEN; S. MILICEV ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 37 KB ๐Ÿ‘ 2 views

3 . The IR spectra indicate the presence of N 2 H + 5 cations with different hydrogen bonding in all three hydrazinium compounds. The weak H bonds in these compounds are further weakened along the decomposition series. According to the powder XRD data, (I) consists of isolated [VF 5 โ€ขH 2 O] 2-octahe