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ChemInform Abstract: Synthesis, Thermal Decomposition and Infrared Spectra of Two New Hydrazinium (1+) Fluorovanadates(III), (N2H5)2VF5×H2O and (N2H5)2VF5.

✍ Scribed by A. RAHTEN; S. MILICEV

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

3 . The IR spectra indicate the presence of N 2 H + 5 cations with different hydrogen bonding in all three hydrazinium compounds. The weak H bonds in these compounds are further weakened along the decomposition series. According to the powder XRD data, (I) consists of isolated [VF 5 •H 2 O] 2-octahedra and (II) is built-up from F-bridged chains of [VF 4 F 2/2 ] octahedra. -(RAHTEN, A.;

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