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Direct Spectroscopic Evidence of Photosensitized O 2 765 nm ( 1 Σ +g → 3 Σ -g ) and O 2 Dimol 634 and 703 nm (( 1 Δ g ) 2 → ( 3 Σ -g ) 2 ) Vibronic Emission in Solution

✍ Scribed by Chou, Pi-Tai; Wei, Guor-Tzo; Lin, Chih-Hung; Wei, Ching-Yen; Chang, Chie-Hung

Book ID
126115820
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
141 KB
Volume
118
Category
Article
ISSN
0002-7863

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Time-resolved emission spectroscopy of 0s ( 'Z: ) and 0s ( 'As) in CCL was used to determine the rate constants kl, , b, and k+ of the triplet state (T,) sensitized formation of the 'Z:, 'As and 'Z; states of 0s. 13 sensitizers of triplet energies 140 GE,< 309 kJ mol-' were investigated. The data ar