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Direct optical resolution of the enantiomers of novel chiral tetrahedral metal clusters by HPLC on a cellulose tris-(3,5-dimethylphenylcarbamate) stationary phase

✍ Scribed by Wenzhi Li; Weiqiang Zhang; Quanyi Zhao; Yongmin Li; Chunlin Ma; Liren Chen; Yuanqi Yin


Publisher
Springer
Year
2004
Tongue
English
Weight
191 KB
Volume
378
Category
Article
ISSN
1618-2650

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πŸ“œ SIMILAR VOLUMES


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## Abstract Direct optical resolution of five novel tetrahedral heterometal cluster enantiomers has been achieved for the first time on a cellulose tris‐(3,5‐dimethylphenylcarbamate) chiral stationary phase, using hexane as the mobile phase with various alcohols as modifiers. UV detection was carri

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Cellulose-tris(3,5-dimethylphenylcarbamate) was prepared after a reported method and was coated onto an aminopropylated mesopore spherical silica gel. The final product was used as a chiral stationary phase of high performance liquid chromatography for the enantioseparation of a series of glycerin s