## Abstract Direct optical resolution of five novel tetrahedral heterometal cluster enantiomers has been achieved for the first time on a cellulose trisβ(3,5βdimethylphenylcarbamate) chiral stationary phase, using hexane as the mobile phase with various alcohols as modifiers. UV detection was carri
Direct optical resolution of the enantiomers of novel chiral tetrahedral metal clusters by HPLC on a cellulose tris-(3,5-dimethylphenylcarbamate) stationary phase
β Scribed by Wenzhi Li; Weiqiang Zhang; Quanyi Zhao; Yongmin Li; Chunlin Ma; Liren Chen; Yuanqi Yin
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 191 KB
- Volume
- 378
- Category
- Article
- ISSN
- 1618-2650
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π SIMILAR VOLUMES
## Abstract Amylose tris(3,5βdimethylphenylcamate) (ADMPC) coated on a kind of small particle silica gel was prepared. On this ADMPC chiral stationary phase (CSP), the direct enantiomeric separation of six novel chiral transition metal tetrahedral clusters has firstly been achieved using __n__βhexa
Cellulose-tris(3,5-dimethylphenylcarbamate) was prepared after a reported method and was coated onto an aminopropylated mesopore spherical silica gel. The final product was used as a chiral stationary phase of high performance liquid chromatography for the enantioseparation of a series of glycerin s